A new oxime ligand in manganese chemistry: a [Mn8] and a [Mn6] cage from the use of 2-dihydroxy-2-phenylacetamidineElectronic supplementary information (ESI) available. CCDC reference numbers 837606and 837607. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/c1dt11455g

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    • Abstract:
      The use of phamidoxH2(phamidoxH2= 2-dihydroxy-2-phenylacetamidine) in manganese cluster chemistry led to the synthesis and characterization of a hexametallic and an octametallic MnIIIcluster, both of which display a S= 3 ground state. [ABSTRACT FROM AUTHOR]
    • Abstract:
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